Mono- and Disamarium Azacryptand Complexes: A Platform for Cooperative Rare-Earth Metal Chemistry.

ABSTRACT: Mono- (H₃LSm) and disamarium complexes (LSm₂) were prepared by reaction of the azacryptand N[(CH₂)₂NHCH₂-p-C₆H₄CH₂NH(CH₂)₂]₃N (H₆L) with 1 or 2 equiv of Sm[N(SiMe₃)₂]₃, respectively. The disamarium complex features free coordination sites on both metal centers available for bridging ligands shielded by phenylenes from tetrahydrofuran (THF) coordination. The reaction of LSm₂ with KCN and 18-crown-6 yielded the adduct [LSm₂-μ-η¹:η¹-CN][K(18-crown-6)(THF)₂] featuring a bridging cyanide. The complexes were characterized by crystallography, electrochemical analysis, NMR,

SUBMITTER: Uher JM 

PROVIDER: S-EPMC9006214 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature