Reversible C-C Bond Cleavage of a Cobalt Diketimide into an Elusive Cobalt Aryl Nitrenoid Complex.

ABSTRACT: The reactivity of (^Tr L)Co (^Tr L=5-mesityl-1,9-(trityl)dipyrrin) toward various aryl azides was examined to elucidate the electronic structure and reactivity of dipyrrinato cobalt aryl nitrenoid complexes. Herein, we demonstrate the synthesis of a Co^II diketimide complex [(^Tr L)Co(NC₆ F₅ )]₂ and its reversible C-C bond cleavage to yield a monomeric Co nitrenoid complex (^Tr L)Co(NC₆ F₅ ). Exposure of [(^Tr L)Co(NC₆ F₅ )]₂ to an excess amount of an H-atom donor cleanly affords the Co^II anilide complex (^Tr L)Co(NHC₆ F₅ ). The half-order decay of [(^Tr L)Co(NC₆ F₅ )]

SUBMITTER: Baek Y 

PROVIDER: S-EPMC9007855 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature