Heterometallic cobalt(ii) calix[6 and 8]arenes: synthesis, structure and electrochemical activity.

ABSTRACT: Heterometallic cobalt p-tert-butylcalix[6 and 8]arenes have been generated from the in situ reaction of lithium reagents (n-BuLi or t-BuOLi) or NaH with the parent calix[n]arene and subsequent reaction with CoBr₂. The reverse route, involving the addition of in situ generated Li[Co(Ot-Bu)₃] to p-tert-butylcalix[6 and 8]arene, has also been investigated. X-ray crystallography reveals the formation of complicated products incorporating differing numbers of cobalt and lithium or sodium centers, often with positional disorder, as well as, in some cases, the retention of halide. The electrochemical analysis revealed several oxidation events related to the subsequent oxidation of Co(ii) centers and the reduction of the

SUBMITTER: Ignaszak A 

PROVIDER: S-EPMC9010074 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature