Homogeneous Precipitation of Lanthanide Oxalates.

ABSTRACT: Oxalic acid is an important separation agent in the technology of lanthanides, actinides, and transition metals. Thanks to the low solubility of the oxalate salts, the metal ions can be easily precipitated into crystalline material, which is a convenient precursor for oxide preparation. However, it is difficult to obtain oxalate monocrystals due to the fast precipitation. We have developed a synthetic route for homogeneous precipitation of oxalates based on the thermal decomposition of oxamic acid. This work primarily concerns lanthanide oxalates; however, since no information was found about oxamic acid, a brief characterization was included. The precipitation method was tested on selected elements (Ce, Pr, Gd, Er, and Yb), for which the kinetics was determined at 100 °C. Several scoping

SUBMITTER: Alemayehu A 

PROVIDER: S-EPMC9016886 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature