Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters.

ABSTRACT: Copper hydrides are important hydrogenation catalysts, but their poor stability hinders the practical applications. Ligand engineering is an effective strategy to tackle this issue. An amidinate ligand, N,N'-Di(5-trifluoromethyl-2-pyridyl)formamidinate (Tf-dpf) with four N-donors has been applied as a protecting agent in the synthesis of stable copper hydride clusters: Cu₁₁H₃(Tf-dpf)₆(OAc)₂ (Cu₁₁) with three interfacial μ₅-H and [Cu₁₂H₃(Tf-dpf)₆(OAc)₂]·OAc (Cu₁₂) with three interstitial μ₆-H. A solvent-triggered reversible interconversion between Cu₁₁ and Cu₁₂ has been observed thanks to the flexibility of Tf-dpf. Cu₁₁ shows hi

SUBMITTER: Liu CY 

PROVIDER: S-EPMC9018778 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature