Molecular Rubies in Photoredox Catalysis.

ABSTRACT: The molecular ruby [Cr(tpe) ₂ ] ³⁺ and the tris(bipyridine) chromium(III) complex [Cr(dmcbpy) ₃ ] ³⁺ as well as the tris(bipyrazine)ruthenium(II) complex [Ru(bpz) ₃ ] ²⁺ were employed in the visible light-induced radical cation [4+2] cycloaddition (tpe = 1,1,1-tris(pyrid-2-yl)ethane, dmcbpy = 4,4'-dimethoxycarbonyl-2,2'-bipyridine, bpz = 2,2'-bipyrazine), while [Cr(ddpd) ₂ ] ³⁺ serves as a control system (ddpd = N,N'-dimethyl-N,N'-dipyridin-2-ylpyridine-2,6-diamine). Along with an updated mechanistic proposal for the Cr^III driven catalytic cycle based on

SUBMITTER: Sittel S 

PROVIDER: S-EPMC9021569 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature