Twisted intramolecular charge transfer of nitroaromatic push-pull chromophores.

ABSTRACT: The structural changes during the intramolecular charge transfer (ICT) of nitroaromatic chromophores, 4-dimethylamino-4'-nitrobiphenyl (DNBP) and 4-dimethylamino-4'-nitrostilbene (DNS) were investigated by femtosecond stimulated Raman spectroscopy (FSRS) with both high spectral and temporal resolutions. The kinetically resolved Raman spectra of DNBP and DNS in the locally-excited and charge-transferred states of the S₁ state appear distinct, especially in the skeletal vibrational modes of biphenyl and stilbene including ν_8a and ν_C=C. The ν_8a of two phenyls and the ν_C=C of the central ethylene group (only for stilbene), which are strongly coupled in the planar geometries, are broken with the twist of nitrophenyl group with the ICT. Time

SUBMITTER: Lee S 

PROVIDER: S-EPMC9023442 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature