Diversity of Metal-Fullerene Framework Structures Regulated by Metal Salts.

ABSTRACT: Taking into account the diversity of fullerene ligands and metal salts, metal-fullerene frameworks (MFFs) present a variety of structures. Currently, the structural control of MFFs mainly relies on the design and synthesis of fullerene ligands, while the influence of metal building units on the structures has been rarely studied. The present work represents a systematical investigation of fullerene-linked supramolecular architectures incorporating different metal salts. Treatment of a bidentate N,N-donors fullerene ligand (L1) with six metal salts ([Zn(NO₃)₂·6H₂O, Cd(NO₃)₂·4H₂O, Cu(NO₃)₂·3H₂O, Cu(OAc)₂·H₂O, FeCl₂·4H₂O and FeCl₃·6H<

SUBMITTER: Wang J 

PROVIDER: S-EPMC9025373 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature