A new family of decanuclear Ln₇Cr₃ clusters exhibiting a magnetocaloric effect.

ABSTRACT: Two dimeric Ln-Cr clusters with formula {Ln(H₂O)₈[Ln₆Cr₃(L)₆(CH₃COO)₆(μ₃-OH)₁₂(H₂O)₁₂]}·(ClO₄)₆·xH₂O (Ln = Gd, x = 35 for 1 and Ln = Dy, x = 45 for 2, HL = 2-pyrazinecarboxylic acid) were obtained by a ligand-controlled hydrolytic method with a mixed ligand system (2-pyrazinecarboxylic acid and acetate). Single crystal structure analysis showed that two trigonal bipyramids of [Gd₃Cr₂(μ₃-OH)₆]⁹⁺ worked as building blocks in constructing the metal-oxo cluster core of [Gd₆Cr₃(μ₃-OH)₁₂]¹⁵⁺ by sharing a common top

SUBMITTER: Yin JJ 

PROVIDER: S-EPMC9033162 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature