Cooperative Stereoinduction in Asymmetric Photocatalysis.

ABSTRACT: Stereoinduction in complex organic reactions often involves the influence of multiple stereocontrol elements. The interaction among these can often result in the observation of significant cooperative effects that afford different rates and selectivities between the matched and mismatched sets of stereodifferentiating chiral elements. The elucidation of matched/mismatched effects in ground-state chemical reactions was a critically important theme in the maturation of modern stereocontrolled synthesis. The development of robust methods for the control of photochemical reactions, however, is a relatively recent development, and similar cooperative stereocontrolling effects in excited-state enantioselective photoreactions have not previously been documented. Herein, we describe a tandem chira

SUBMITTER: Chapman SJ 

PROVIDER: S-EPMC9033210 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature