Efficient removal of bisphenol pollutants on imine-based covalent organic frameworks: adsorption behavior and mechanism.

ABSTRACT: The extensive use of bisphenol analogues in industry has aggravated the contamination of the water environment, and how to effectively remove them has become a research hotspot. This study presents two imine-based covalent organic frameworks with different pore sizes (COFs) [TAPB (1,3,5-tris(4-aminophenyl)benzene)-Dva (2,5-divinylterephthaldehyde)-PDA (terephthalaldehyde) (COF-1), and TAPB (1,3,5-tris(4-aminophenyl)benzene)-Dva (2,5-divinylterephthaldehyde)-BPDA (biphenyl dialdehyde) (COF-2)], which have achieved the efficient adsorption of bisphenol S (BPS) and bisphenol A (BPA). The maximum adsorption capacity of COF-2 for BPS and BPA obtained from Langmuir isotherms were calculated as 200.00 mg g^-1 and 149.25 mg g^-1. Both hydrogen bonding and π-π interactions might

SUBMITTER: Fu D 

PROVIDER: S-EPMC9033470 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature