Ontology highlight
ABSTRACT:
SUBMITTER: Li Y
PROVIDER: S-EPMC9034046 | biostudies-literature | 2021 Jun
REPOSITORIES: biostudies-literature
Li Yuwen Y Li Sen S Du Xin X Gu Zhongze Z
RSC advances 20210614 34
In this paper we provide new insight into the disulfide-yne photo reaction, which is similar but different from the well-known thiol-yne photoclick reaction. We show that, unlike the stable product generated from thiol-yne chemistry, the vinyl dithioether structure obtained from disulfide-yne reaction exhibits unique reactivity with thiols and disulfides, which can be used for surface photochemistry to fabricate reactive and dynamic surfaces. The possible mechanism for the unique reactivity of v ...[more]