Mechanistic effects of blending formic acid with ethanol on Pd activity towards formic acid oxidation in acidic media.

ABSTRACT: The direct formic acid fuel cell (DFAFC) is one of the most promising direct liquid fuel cells. Pd is the most active catalyst towards formic oxidation, however, it suffers from CO-like poisoning and instability in acidic media. Blending formic acid with ethanol is known to synergistically enhance the Pt catalytic activity of Pt. However, it has not been studied in the case of Pd. In this study, ethanol/formic acid blends were tested, aiming at understanding the effect of ethanol on the formic acid oxidation mechanism at Pd and how the direct and indirect pathways could be affected. The blends consisted of different formic acid (up to 4 M) and ethanol (up to 0.5 M) concentrations. The catalytic activity of a 40% Pd/C catalyst was tested in 0.1 M H₂SO₄ + XFA + <

SUBMITTER: Al Najjar T 

PROVIDER: S-EPMC9034384 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature