Atomistic and machine learning studies of solute segregation in metastable grain boundaries.

ABSTRACT: The interaction of alloying elements with grain boundaries (GBs) influences many phenomena, such as microstructural evolution and transport. While GB solute segregation has been the subject of active research in recent years, most studies focus on ground-state GB structures, i.e., lowest energy GBs. The impact of GB metastability on solute segregation remains poorly understood. Herein, we leverage atomistic simulations to generate metastable structures for a series of [001] and [110] symmetric tilt GBs in a model Al-Mg system and quantify Mg segregation to individual sites within these boundaries. Our results show large variations in the atomic Voronoi volume due to GB metastability, which are found to influence the segregation energy. The atomistic data are then used to train a Gaussian P

SUBMITTER: Mahmood Y 

PROVIDER: S-EPMC9035190 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature