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An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties.

ABSTRACT: Two new copper(ii) complexes [Cu2(L)2(OAc)2(H2O)2] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL2] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling.

SUBMITTER: Petrenko YP 

PROVIDER: S-EPMC9036593 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature

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An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties.

Petrenko Yuliia P YP   Piasta Karolina K   Khomenko Dmytro M DM   Doroshchuk Roman O RO   Shova Sergiu S   Novitchi Ghénadie G   Toporivska Yuliya Y   Gumienna-Kontecka Elzbieta E   Martins Luísa M D R S LMDRS   Lampeka Rostyslav D RD  

RSC advances 20210702 38

Two new copper(ii) complexes [Cu<sub>2</sub>(L)<sub>2</sub>(OAc)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL<sub>2</sub>] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling. ...[more]