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Grafting of thermotropic fluorinated mesogens on polysiloxane to improve the processability of linear low-density polyethylene.

ABSTRACT: In this study, a series of polysiloxane grafted with thermotropic fluorinated mesogens (TSCPFLCP) is designed and synthesized. The TSCPFLCP exhibits a typical smectic liquid crystal phase, and shows a high thermal decomposition temperature at 335.6 °C. After blending with LLDPE, the balance melt torque of LLDPE/TSCPFLCP is decreased by 42% at 0.5 wt% TSCPFLCP, and the corresponding power law index is increased to 0.45. The flowing activation energy of the optimized LLDPE/TSCPFLCP blend is lower than that of pure LLDPE at the same shear rate, indicating that TSCPFLCP reduced the sensitivity of the apparent melt viscosity of LLDPE to both shear rate and temperature. This contributes to the broadening of the LLDPE processing window. On the other hand, TSCPFLCP is also found beneficial in ameliorating melt fracture during LLDPE extrusion. Furthermore, the mechanical properties of LLDPE/TSCPFLCP blends, such as tensile strength, elastic modulus and elongation at break, are also enhanced significantly at 0.5 wt% TSCPFLCP. Altogether, TSCPFLCP has been proven an effective processing aid to improve the processability and toughness of LLDPE.

SUBMITTER: Wu W

PROVIDER: S-EPMC9036815 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature

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Grafting of thermotropic fluorinated mesogens on polysiloxane to improve the processability of linear low-density polyethylene.

Wu Wenqing W Li Pan P Wang Xiaohang X Zhang Baoyan B

RSC advances 20220425 20

In this study, a series of polysiloxane grafted with thermotropic fluorinated mesogens (TSCPFLCP) is designed and synthesized. The TSCPFLCP exhibits a typical smectic liquid crystal phase, and shows a high thermal decomposition temperature at 335.6 °C. After blending with LLDPE, the balance melt torque of LLDPE/TSCPFLCP is decreased by 42% at 0.5 wt% TSCPFLCP, and the corresponding power law index is increased to 0.45. The flowing activation energy of the optimized LLDPE/TSCPFLCP blend is lower ...[more]

PMID: 35480351

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Project description:The issue of discharging waste, especially heavy metals from industrial activities into the environment, not only adversely impacts environmental quality but also has impacts on communities and human health. Removal and reduction of heavy metal contamination in rivers and wastewater are, therefore, critical initiatives that require significant attention. This work studied the removal of heavy metals, including Zn(II), Cu(II), As(III), and Pb(II) by utilizing an upcycled amidoxime low-density polyethylene sheet (AO-sheet). The synthesized AO-sheet was analyzed for various physical properties, including scanning electron microscope, energy-dispersive x-ray spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis. For the batch adsorption experiment, parameters affecting adsorption capacity were studied: initial concentration, submerging time, and pH. Adsorption isotherms were also studied. The results of the heavy metal adsorption study showed that the initial concentration was the most significant parameter; the higher the initial concentration, the greater the adsorption capacity. The adsorption capacity of Zn(II) and Pb(II) increased with submersion time, which achieved 21.07 and 0.855 mg/g-adsorbent, respectively, after four weeks of submersion under the highest initial concentration studied. The adsorption capacity of Cu(II) was 7.98 mg/g-adsorbent after two weeks of optimal adsorption duration under the highest initial concentration studied. The adsorption capacity of As(II) was 1.07 mg/g-adsorbent after one week of optimal submersion time under the highest initial concentration studied. Moreover, the appropriate pH range for effective adsorption of Zn(II), Cu(II), and Pb(II) was identified as 8-9, while for As(III), it was 6-8, with an adsorption duration of 0.43 weeks (3 days). From the Langmuir isotherm, it was found that the adsorption of this work was characterized by monolayer adsorption. The results demonstrate that the AO-sheet can be effectively used to remove heavy metals from wastewater. Its potential for reusability was up to 8 cycles, with the Zn(II) adsorption capacity being reduced to about 20.37%.

Dataset Information

Grafting of thermotropic fluorinated mesogens on polysiloxane to improve the processability of linear low-density polyethylene.

Publications

Grafting of thermotropic fluorinated mesogens on polysiloxane to improve the processability of linear low-density polyethylene.

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