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Formation of synthetically relevant CF₃-substituted phenonium ions in superacid media.

ABSTRACT: Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF₃-substituted phenonium ions can be generated to furnish original CF₃-substituted dihydrostilbenes of interest.

SUBMITTER: Fernandes AJ

PROVIDER: S-EPMC9036966 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature

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Formation of synthetically relevant CF3-substituted phenonium ions in superacid media.

Fernandes Anthony J AJ Michelet Bastien B Panossian Armen A Martin-Mingot Agnès A Leroux Frédéric R FR Thibaudeau Sébastien S

RSC advances 20210726 41

Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF3-substituted phenonium ions can be generated to furnish original CF3-substituted dihydrostilbenes of interest. ...[more]

PMID: 35478903

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