Direct synthesis of shaped MgAPO-11 molecular sieves and the catalytic performance in n-dodecane hydroisomerization.

ABSTRACT: In industrial application, molecular sieves are usually used in a certain shape. This requires the addition of binder and causes the reduction of both the molecular sieve content and catalytic performance. Herein, pseudo-boemite was mixed with deionized water at room temperature, followed by the drop-wise addition of phosphoric acid, magnesium acetate solution, hydrofluoric acid, di-n-propylamine and 1-ethyl-3-methyl imidazolium bromide with vigorous stirring. The molar ratio of Al₂O₃ : P₂O₅ : MgO : HF : DPA : [EMIm]Br : H₂O in the gel was 1 : 1 : 0.03 : 0.18 : 0.4 : 1 : 45. Then the gel was dried, extruded and directly crystallized to form a shaped MgAPO-11 molecular sieve. X-ray diffraction, scanning electron microscopy, N

SUBMITTER: Wang P 

PROVIDER: S-EPMC9036975 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature