A bifunctional lead-iron oxyfluoride, PbFeO₂F, that functions as a visible-light-responsive photoanode and an electrocatalyst for water oxidation.

ABSTRACT: The oxyfluoride PbFeO₂F was investigated as a photoanode material and as an electrocatalyst for water oxidation. PbFeO₂F powder, which was synthesized by a high-pressure method and had an estimated bandgap of 2.1 eV, was deposited onto a fluorine-doped tin oxide (FTO) substrate. Mott-Schottky plot measurements for the PbFeO₂F/FTO electrode showed n-type semiconductivity of PbFeO₂F, with a flat-band potential of +0.53 ± 0.05 V vs. reversible hydrogen electrode (RHE). The PbFeO₂F/FTO electrode, which was modified with a conductive TiO₂ layer and a cobalt phosphate water-oxidation cocatalyst, showed a clear anodic photocurrent in aqueous K₃PO₄ solution under visible-light irradiation (λ < 600

SUBMITTER: Mizuochi R 

PROVIDER: S-EPMC9037018 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature