Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids.

ABSTRACT: Fast (60 kHz) magic angle spinning solid-state NMR allows very sensitive proton detection in highly paramagnetic organometallic powders. We showcase this technique with the complete assignment of ¹H and ¹³C resonances in a high-spin Fe(ii) polymerisation catalyst with less than 2 mg of sample at natural abundance.

SUBMITTER: Blahut J 

PROVIDER: S-EPMC9040908 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature