Structural investigation of three distinct amorphous forms of Ar hydrate.

ABSTRACT: Three amorphous forms of Ar hydrate were produced using the crystalline clathrate hydrate Ar·6.5H₂O (structure II, Fd3̄m, a ≈ 17.1 Å) as a precursor and structurally characterized by a combination of isotope substitution (³⁶Ar) neutron diffraction and molecular dynamics (MD) simulations. The first form followed from the pressure-induced amorphization of the precursor at 1.5 GPa at 95 K and the second from isobaric annealing at 2 GPa and subsequent cooling back to 95 K. In analogy to amorphous ice, these amorphs are termed high-density amorphous (HDA) and very-high-density amorphous (VHDA), respectively. The third amorph (recovered amorphous, RA) was obtained when recovering VHDA to ambient pressure (at 95 K). The three amorphs have distinctly diff

SUBMITTER: Brant Carvalho PHB 

PROVIDER: S-EPMC9041099 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature