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Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe₂TiO₅ nanofibers.

ABSTRACT: Nanostructured Fe₂TiO₅ (pseudobrookite), a mixed metal oxide material holds significant promise for utilization in energy and environmental applications. However, its full application is still hindered due to the difficulty to synthesize monophasic Fe₂TiO₅ with high crystallinity and a large specific surface area. Herein, Fe₂TiO₅ nanofibers were synthesized via a versatile and low-cost electrospinning method, followed by a calcination process at different temperatures. We found a significant effect of the calcination process and its duration on the crystalline phase in the form of either pseudobrookite or pseudobrookite-hematite-rutile and the morphology of calcined nanofibers. The crystallite size increased whereas the specific surface area decreased with an increase in calcination temperature. At higher temperatures, the growth of Fe₂TiO₅ nanoparticles and simultaneous coalescence of small particles was noted. The highest specific surface area was obtained for the sample calcined at 500 °C for 6 h (S _BET = 64.4 m² g^-1). This work opens new opportunities in the synthesis of Fe₂TiO₅ nanostructures using the electrospinning method and a subsequent optimized calcination process for energy-related applications.

SUBMITTER: Vasiljevic ZZ

PROVIDER: S-EPMC9042236 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers.

Vasiljević Zorka Ž ZŽ Dojčinović Milena P MP Vujančević Jelena D JD Spreitzer Matjaž M Kovač Janez J Bartolić Dragana D Marković Smilja S Janković-Čaštvan Ivona I Tadić Nenad B NB Nikolić Maria Vesna MV

RSC advances 20210901 51

Nanostructured Fe2TiO5 (pseudobrookite), a mixed metal oxide material holds significant promise for utilization in energy and environmental applications. However, its full application is still hindered due to the difficulty to synthesize monophasic Fe2TiO5 with high crystallinity and a large specific surface area. Herein, Fe2TiO5 nanofibers were synthesized via a versatile and low-cost electrospinning method, followed by a ...[more]

PMID: 35495544

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Project description:TiO2 nanofibers were fabricated by combination of sol-gel and electrospinning techniques. Ag-doped TiO2 nanofibers with different Ag contents were prepared by two different methods (in situ electrospinning or wetness impregnation of Ag on TiO2 nanofibers) and heat treated at 500 °C for 2 h under an air or N2 atmosphere. The obtained catalysts were characterized by field emission scanning electron microscopy, X-ray diffraction, photoluminescence, and N2 adsorption analyzed by the Brunauer-Emmett-Teller (BET) method. Photocatalytic glucose conversions with electrospun TiO2 and Ag-doped TiO2 nanofibers for production of high-value products were carried out. From different doping methods, the results indicated that 1 wt % Ag-TiO2 nanofibers prepared by an in situ method with calcination under N2 achieved the highest glucose conversion (85.49%). From several Ag loading contents (i.e., 0, 1, 2, and 4 wt %) in Ag-doped TiO2 nanofibers, the nanofibers exhibited different glucose conversions [in order of 2 wt % (99.65%) > 1 wt % (85.49%) > 4 wt % (77.72%) > 0 wt % (29.64%)]. Arabinose, xylitol, gluconic acid, and formic acid were found as the high-value chemicals with the photocatalytic reaction of TiO2 and Ag-doped TiO2 nanofibers under UVA irradiation. Product yields of each converted chemicals from different photocatalysts from different Ag loading contents showed relatively same trends with the glucose conversion. From all results, it can be concluded that the good characteristics of 2 wt % Ag-TiO2 nanofibers such as the smallest anatase crystallite size (8.25 nm) and the highest specific surface area (S BET = 53.69 m2/g) promoted the highest photocatalytic activity. Additionally, TiO2 and Ag-doped TiO2 nanofibers exhibited higher photocatalytic performance for glucose conversion than commercial TiO2 (P25) and synthesized TiO2 nanoparticles. Finally, Ag-doped TiO2 nanofibers showed recycling ability with high photocatalytic glucose conversion after four-time use.

Dataset Information

Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe₂TiO₅ nanofibers.

Publications

Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe<sub>2</sub>TiO<sub>5</sub> nanofibers.

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