Photoelectron photofragment coincidence spectroscopy of carboxylates.

ABSTRACT: Photoelectron-photofragment coincidence (PPC) spectroscopy is a powerful technique for studying the decarboxylation dynamics of carboxyl radicals. Measurement of photoelectron and photofragment kinetic energies in coincidence provides a kinematically complete measure of the dissociative photodetachment (DPD) dynamics of carboxylate anions. PPC spectroscopy studies of methanoate, ethanoate, propanoate, 2-butenoate, benzoate, p-coumarate and the oxalate monoanion are reviewed. All of the systems studied undergo decarboxylation via a two-body DPD channel i.e., driven by the thermodynamic stability of CO₂. Additionally, decarboxylation is observed via a three-body ionic photodissociation channel for p-coumarate. In some cases photodetachment also r

SUBMITTER: Gibbard JA 

PROVIDER: S-EPMC9042398 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature