Chiral fluorescence recognition of glutamine enantiomers by a modified Zr-based MOF based on solvent-assisted ligand incorporation.

ABSTRACT: In this study, three types of chiral fluorescent zirconium-based metal-organic framework materials were synthesized using l-dibenzoyl tartaric acid as the chiral modifier by the solvent-assisted ligand incorporation method, which was the porous coordination network yellow material, denoted as PCN-128Y. PCN-128Y-1 and PCN-128Y-2 featured unique chiral selectivity for the Gln enantiomers amongst seven acids and the highly stable luminescence property, which were caused by the heterochiral interaction and aggregation-induced emission. Furthermore, a rapid fluorescence method for the chiral detection of glutamine (Gln) enantiomers was developed. The homochiral crystals of PCN-128Y-1 displayed enantiodiscrimination in the quenching by d-Gln such that the ratio of enantioselectivity was 2.0 in 3

SUBMITTER: Shili Q 

PROVIDER: S-EPMC9043823 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature