Unexpected reactivity related to support effects during xylose hydrogenation over ruthenium catalysts.

ABSTRACT: Xylose is a major component of hemicelluloses. In this paper, its hydrogenation to xylitol in aqueous medium was investigated with two Ru/TiO₂ catalysts prepared with two commercial TiO₂ supports. A strong impact of the support on catalytic performance was evidenced. Ru/TiO₂-R led to fast and selective conversion of xylose (100% conversion in 2 h at 120 °C with 99% selectivity) whereas Ru/TiO₂-A gave a slower and much less selective transformation (58% conversion in 4 h at 120 °C with 17% selectivity) with the formation of several by-products. Detailed characterization of the catalysts with ICP, XRD, FTIR, TEM, H₂ chemisorption, N₂ porosimetry, TPR and acid-base titration was performed to elucidate the role of each support.

SUBMITTER: Vilcocq L 

PROVIDER: S-EPMC9044411 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature