Ultrasound-mediated synthesis of nanoporous fluorite-structured high-entropy oxides toward noble metal stabilization.

ABSTRACT: High-entropy oxides (HEOs) are an emerging class of advanced ceramic materials capable of stabilizing ultrasmall nanoparticle catalysts. However, their fabrication still relies on high-temperature thermal treatment methodologies affording nonporous architectures. Herein, we report a facile synthesis of single-phase, fluorite-structured HEO nanocrystals via an ultrasound-mediated co-precipitation strategy under ambient conditions. Within 15 min of ultrasound exposure, high-quality fluorite-structured HEO (CeHfZrSnErO_x) was generated as ultrasmall-sized particles with high surface area and high oxygen vacancy concentration. Taking advantage of these unique structural features, palladium was introduced and stabilized in the form of highly dispersed Pd nanoclusters within the CeHfZr

SUBMITTER: Okejiri F 

PROVIDER: S-EPMC9048099 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature