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Rapid synthesis of hierarchical SSZ-13 zeolite microspheres via a fluoride-assisted in situ growth route using aluminum isopropoxide as aluminum source.

ABSTRACT: Hierarchical SSZ-13 zeolite microspheres were quickly synthesized by adding a small quantity of hydrofluoric acid in the starting gel using aluminum isopropoxide as aluminum source. The as-synthesized hierarchical SSZ-13 crystals with high crystallinity, pore volume and external surface area were obtained within 12 h, whereas a much longer time (144 h) was necessary to synthesize a fully crystalline zeolite in a fluorine free system. The obtained hierarchical SSZ-13 catalysts showed excellent MTO performance together with considerably prolonged catalytic lifetime and improved selectivity of light olefins in comparison with the conventional microporous SSZ-13.

SUBMITTER: Bing L

PROVIDER: S-EPMC9048864 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Rapid synthesis of hierarchical SSZ-13 zeolite microspheres via a fluoride-assisted in situ growth route using aluminum isopropoxide as aluminum source.

Bing Liancheng L Liu Jiajia J Yi Kaifeng K Li Fangni F Han Dezhi D Wang Fang F Wang Guangjian G

RSC advances 20200122 6

Hierarchical SSZ-13 zeolite microspheres were quickly synthesized by adding a small quantity of hydrofluoric acid in the starting gel using aluminum isopropoxide as aluminum source. The as-synthesized hierarchical SSZ-13 crystals with high crystallinity, pore volume and external surface area were obtained within 12 h, whereas a much longer time (144 h) was necessary to synthesize a fully crystalline zeolite in a fluorine free system. The obtained hierarchical SSZ-13 catalysts showed excellent MT ...[more]

PMID: 35497729

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