Lanthanide complexes based on a conjugated pyridine carboxylate ligand: structures, luminescence and magnetic properties.

ABSTRACT: Three lanthanide compounds have been synthesized, namely, {[Dy₂(bpda)₃(H₂O)₃]₄·2H₂O}(Dy-1), {[Sm(bpda)₂·(H₂O)]·H₂O} _n (Sm-2) and {[Tb₂(bpda)₃(H₂O)₃]₄·2H₂O} (Tb-3) (H₂bpda = 2,2'-bipyridine-6,6'-dicarboxylic acid). Their structures were determined by single crystal X-ray diffraction and characterized by elemental analysis, infrared spectroscopy and thermogravimetric analysis. Dy-1 and Tb-3 are isostructural with a conjugate bimolecular four-nuclear cluster structure constructed with intramolecular hydrogen bonds and they form a 3D supramolecular structure with intermolecular hydrogen bonding. Sm-2 is

SUBMITTER: Li RF 

PROVIDER: S-EPMC9049638 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature