Photocatalytic production of dihydroxyacetone from glycerol on TiO₂ in acetonitrile.

ABSTRACT: In this paper, photocatalytic production of dihydroxyacetone (DHA) from glycerol in acetonitrile on TiO₂ was investigated. HPLC-MS analysis showed that glycerol was converted to DHA, glyceraldehyde (GAD), glyceric acid and several other chemicals. Using acetonitrile as the reaction medium instead of water not only provided a more selective process for production of DHA but also increased the glycerol conversion. After 300 min, with 1 g L^-1 catalyst loading and 4 mM initial glycerol concentration, glycerol conversion and DHA selectivity were 96.8% and 17.8% in acetonitrile compared to 36.1% and 14.7% in water, respectively. The half-life of glycerol decreased by a factor of 6.2, from 467 min to 75 min, by changing the solvent from water to acetonitrile. Experiments usi

SUBMITTER: Imbault AL 

PROVIDER: S-EPMC9049670 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature