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Novel polyimides containing flexible carbazole blocks with electrochromic and electrofluorescencechromic properties.

ABSTRACT: A series of polyimides (PIs) were prepared by polycondensation of a diamine monomer with five anhydrides (1,2,4,5-benzenetetracarboxylic anhydride (BTA), 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTD), 3,3',4,4'-biphenyltetracarboxylic dianhydride (BTD), 4-[(1,3-dihydro-1,3-dioxo-5-isobenzofuranyl)oxy]-1,3-isobenzofurandione (DDII), and 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BPTD)), which have anodic electrochromic (EC) properties. These PIs not only show good solubility and thermal stability, but also demonstrate stable electrochemical oxidation behavior and good EC properties, and the highest retained electroactivity reaches 99% after 600 cycles. In addition, the series of PIs exhibit excellent electrofluorescencechromic (EFC) properties. Therefore, the novel materials will contribute to the application of EC or EFC displays in the future.

SUBMITTER: Zheng R

PROVIDER: S-EPMC9049831 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Novel polyimides containing flexible carbazole blocks with electrochromic and electrofluorescencechromic properties.

Zheng Rongrong R Huang Tao T Zhang Zhipeng Z Sun Zhiyao Z Niu Haijun H Wang Cheng C Wang Wen W

RSC advances 20200214 12

A series of polyimides (PIs) were prepared by polycondensation of a diamine monomer with five anhydrides (1,2,4,5-benzenetetracarboxylic anhydride (BTA), 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTD), 3,3',4,4'-biphenyltetracarboxylic dianhydride (BTD), 4-[(1,3-dihydro-1,3-dioxo-5-isobenzofuranyl)oxy]-1,3-isobenzofurandione (DDII), and 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BPTD)), which have anodic electrochromic (EC) properties. These PIs not only show good solubility and th ...[more]

PMID: 35493867

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