Structural analysis of cross-linked poly(vinyl alcohol) using high-field DNP-NMR.
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ABSTRACT: Poly(vinyl alcohol) (PVOH) is a water-soluble synthetic polymer, widely used in materials for functional films and moldings, fiber fabric sizing agents, paper coating resins, and adhesives. PVOH is mainly applied in the form of an aqueous solution, yet after its application, insolubility (water resistance) is required. To achieve this, additives are introduced. These additives used with PVOH are cross-linking agents which react with the hydroxyl groups and modified functional groups in PVOH. Because of the poor reactivity of unmodified PVOH, it does not react with cross-linking agents that have functional reactive groups. Therefore, modified PVOH that reacts with a cross-linking agent more successfully is required. These chemical bonding sites are so low in abundance that it is difficult t
SUBMITTER: Kanda T
PROVIDER: S-EPMC9049923 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
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