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A flower-like CoS2/MoS2 heteronanosheet array as an active and stable electrocatalyst toward the hydrogen evolution reaction in alkaline media.


ABSTRACT: CoS2/MoS2 heteronanosheet arrays (HNSAs) with vertically aligned flower-like architectures are fabricated through in situ topotactic sulfurization of CoMoO4 nanosheet array (NSA) precursors on conductive Ni foam. CoMoO4 NSAs are prepared by a self-template hydrothermal method without using any hard template and surfactant. Benefiting from a 3D flower-like architecture constituted by ultrathin nanosheets with abundant exposed heterointerfaces as highly active sites and predesigned void spaces, the as-synthesized CoS2/MoS2 HNSAs exhibit an excellent hydrogen evolution reaction (HER) performance with a low overpotential of 50 mV at 10 mA cm-2, and a small Tafel slope of 76 mV dec-1 in 1.0 M KOH, whi

SUBMITTER: Shi M 

PROVIDER: S-EPMC9050031 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature