Facile fabrication of bimetallic Fe-Mg MOF for the synthesis of xanthenes and removal of heavy metal ions.

ABSTRACT: This work reported the preparation of Mg-MOF, Fe-MOF and Fe-Mg MOF by a solvothermal technique and their characterization with FT-IR, XRD, SEM, EDS, TEM and S _BET analyses. The nanoparticle diameter ranged from 3.1 to 10.9 nm. The acidity of the MOFs was measured by nonaqueous potentiometric titration of n-butylamine. It was observed that the formation of a bimetallic MOF sharply increases the surface acidity and the catalytic activity. The catalytic results of the Fe-Mg MOF catalyzing the synthesis of 14-aryl-14-H-dibenzo[a,j]xanthenes in comparison with those of parent MOFs showed a higher yield of the desired product in a lower time and among various Fe : Mg, the (0.6 : 1) Fe-Mg MOF showed the highest catalytic activity and acidity. Even aft

SUBMITTER: Abo El-Yazeed WS 

PROVIDER: S-EPMC9050136 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature