Vacancy-induced interfacial ferromagnetic features in SmFeO₃-filled graphitic carbon foam.

ABSTRACT: We report a novel structural and magnetic investigation of carbon foam (CFM) materials filled with SmFeO₃ crystals produced by (1) high temperature fusion between Sm₂O₃- and Fe₃C-filled carbon onions and (2) annealing of iron filled CFM with nanosized Sm₂O₃. Presence of a defect-rich monolayer-like CFM arrangement characterized by sharp interfaces with a SmFeO₃ single-crystal phase is demonstrated through TEM and HRTEM. Further, the presence of intense sp³-rich features with variable carbonate content is evidenced by XPS and Raman spectroscopy. Complementary VSM, SQUID and ESR show also presence of intrinsic magnetization features which appeared to be attributable to the interfacial vacancy-rich regions

SUBMITTER: Fayazi M 

PROVIDER: S-EPMC9050209 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature