Synthesis, crystal structures and magnetic properties of two heterometallic {Ln8Cr4} (Ln = Gd3+ and Tb3+) complexes with one-dimensional wave chain structure.
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ABSTRACT: Two isomorphic heterometallic 3d-4f cluster-based materials, formulated [Gd8Cr4(IN)18(μ3-O)2(μ3-OH)6(μ4-O)4(H2O)10]·13H2O (1) and [Tb8Cr4(IN)18(μ3-O)2(μ3-OH)6(μ4-O)4(H2O)10]·13H2O (2) (abbreviation: {Ln8Cr4}: Ln = Gd3+ (1); Tb3+ (2); HIN = isonicotinic acid), were achieved by hydro-/solvothermal method through using the ligand HIN. X-ray diffraction analysis illustrates eight lanthanide ions (Ln = Gd3+, Tb3+) and four transition-metal ions (Cr3+) of {Ln
SUBMITTER: Han YM
PROVIDER: S-EPMC9050496 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
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