Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Flexible and low-k polymer featuring hard-soft-hybrid strategy.

ABSTRACT: One of the main challenges for dielectric materials for advanced microelectronics is their high dielectric value and brittleness. In this study, we adopted a hard-soft-hybrid strategy and successfully introduced a hard, soft segment and covalent crosslinked structural unit into a hybridized skeleton via copolymerization of polydimethylsiloxane (PDMS), benzocyclobutene (BCB) and double-decker-shaped polyhedral silsesquioxanes (DDSQ) by a platinum-catalyzed hydrosilylation reaction, thus producing a random copolymer (PDBD) with a hybridized skeleton in the main chain. PDBD exhibited high molecular weight and thermal curing action without any catalyst. More importantly, the cured copolymer displayed high flexibility, high thermal stability and low dielectric constant, evidencing its potential applications in high-performance dielectric materials.

SUBMITTER: Hu H

PROVIDER: S-EPMC9050597 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Flexible and low-<i>k</i> polymer featuring hard-soft-hybrid strategy.

Hu Huan H Ma Jiajun J Yuan Wen W Peng Qiuxia Q Yang Junxiao J

RSC advances 20200324 20

One of the main challenges for dielectric materials for advanced microelectronics is their high dielectric value and brittleness. In this study, we adopted a hard-soft-hybrid strategy and successfully introduced a hard, soft segment and covalent crosslinked structural unit into a hybridized skeleton <i>via</i> copolymerization of polydimethylsiloxane (PDMS), benzocyclobutene (BCB) and double-decker-shaped polyhedral silsesquioxanes (DDSQ) by a platinum-catalyzed hydrosilylation reaction, thus pr ...[more]

PMID: 35496624

Similar Datasets

Correlations in Hard- and Soft-Core Generic Polymer Models.

Project description:Generic polymer models capturing the chain connectivity and the non-bonded excluded-volume interactions between polymer segments can be classified into hard- and soft-core models depending on their non-bonded pair potential. Here we compared the correlation effects on the structural and thermodynamic properties of the hard- and soft-core models given by the polymer reference interaction site model (PRISM) theory, and found different behaviors of the soft-core models at large invariant degree of polymerization (IDP) depending on how IDP is varied. We also proposed an efficient numerical approach, which enables us to accurately solve the PRISM theory for chain lengths as large as 106.

| S-EPMC10007592 | biostudies-literature

Flexible Soft-Printed Polymer Films with Tunable Plasmonic Properties.

Project description:Noble metal nanoparticles (NPs) and particularly gold (Au) have become emerging materials in recent decades due to their exceptional optical properties, such as localized surface plasmons. Although multiple and relatively simple protocols have been developed for AuNP synthesis, the functionalization of solid surfaces composed of soft matter with AuNPs often requires complex and multistep processes. Here we developed a facile approach for functionalizing soft adhesive flexible films with plasmonic AuNPs. The synthetic route is based on preparing Au nanoislands (AuNI) (ca. 2-300 nm) on a glass substrate followed by hydrophobization of the functionalized surface, which in turn, allows efficient transfer of AuNIs to flexible adhesive films via soft-printing tape lithography. Here we show that the AuNI structure remained intact after the hydrophobization and soft-printing procedures. The AuNI-functionalized flexible films were characterized by various techniques, revealing unique characteristics such as tunable localized plasmon resonance and Raman enhancement factors beneficial for chemical and biological sensing applications.

| S-EPMC10636776 | biostudies-literature

Polymer-metal hybrid transparent electrodes for flexible electronics.

Project description:Despite nearly two decades of research, the absence of ideal flexible and transparent electrodes has been the largest obstacle in realizing flexible and printable electronics for future technologies. Here we report the fabrication of 'polymer-metal hybrid electrodes' with high-performance properties, including a bending radius <1 mm, a visible-range transmittance>95% and a sheet resistance <10 Ω sq(-1). These features arise from a surface modification of the plastic substrates using an amine-containing nonconjugated polyelectrolyte, which provides ideal metal-nucleation sites with a surface-density on the atomic scale, in combination with the successive deposition of a facile anti-reflective coating using a conducting polymer. The hybrid electrodes are fully functional as universal electrodes for high-end flexible electronic applications, such as polymer solar cells that exhibit a high power conversion efficiency of 10% and polymer light-emitting diodes that can outperform those based on transparent conducting oxides.

| S-EPMC4382999 | biostudies-literature

Iron-clad fibers: a metal-based biological strategy for hard flexible coatings.

Project description:The extensible byssal threads of marine mussels are shielded from abrasion in wave-swept habitats by an outer cuticle that is largely proteinaceous and approximately fivefold harder than the thread core. Threads from several species exhibit granular cuticles containing a protein that is rich in the catecholic amino acid 3,4-dihydroxyphenylalanine (dopa) as well as inorganic ions, notably Fe3+. Granular cuticles exhibit a remarkable combination of high hardness and high extensibility. We explored byssus cuticle chemistry by means of in situ resonance Raman spectroscopy and demonstrated that the cuticle is a polymeric scaffold stabilized by catecholato-iron chelate complexes having an unusual clustered distribution. Consistent with byssal cuticle chemistry and mechanics, we present a model in which dense cross-linking in the granules provides hardness, whereas the less cross-linked matrix provides extensibility.

| S-EPMC3087814 | biostudies-literature

Multifunctional Hard Yet Flexible Coatings Fabricated Using a Universal Step-by-Step Strategy.

Project description:Hard yet flexible coatings with multi-functionalities are useful for foldable displays and marine industries but rare. In this study, a highly cross-linked multifunctional hybrid coating with ceramic-like hardness and polymer-like flexibility is reported. The coating is prepared via a step-by-step strategy, where two types of epoxy-oligosiloxane nanoclusters are first synthesized by sol-gel chemistry, and amine-terminated curing agents are used to cross-link them at room temperature. The coating is highly transparent (>92% transmittance), hard (6-7H), and flexible (10 mm bending diameter) because of the unique combination of siloxane nanoclusters and polymer networks. Meanwhile, since the coating contains fouling-resistant telomer and low-surface-tension liquid lubricant polydimethylsiloxane (PDMS), it exhibits excellent anti-biofouling and self-cleaning properties. The results indicate that the mechanical and antifouling properties of the coating can be easily tuned and prove that the step-by-step strategy is a promising and universal method. The novel coatings can meet the needs of applications in foldable displays, marine industries, and other fields.

| S-EPMC9109054 | biostudies-literature

Flexible Memristor Devices Using Hybrid Polymer/Electrodeposited GeSbTe Nanoscale Thin Films.

Project description:We report on the development of hybrid organic-inorganic material-based flexible memristor devices made by a fast and simple electrochemical fabrication method. The devices consist of a bilayer of poly(methyl methacrylate) (PMMA) and Te-rich GeSbTe chalcogenide nanoscale thin films sandwiched between Ag top and TiN bottom electrodes on both Si and flexible polyimide substrates. These hybrid memristors require no electroforming process and exhibit reliable and reproducible bipolar resistive switching at low switching voltages under both flat and bending conditions. Multistate switching behavior can also be achieved by controlling the compliance current (CC). We attribute the switching between the high resistance state (HRS) and low resistance state (LRS) in the devices to the formation and rupture of conductive Ag filaments within the hybrid PMMA/GeSbTe matrix. This work provides a promising route to fabricate flexible memory devices through an electrodeposition process for application in flexible electronics.

| S-EPMC9791617 | biostudies-literature

Flexible All-Inorganic Perovskite Photodetector with a Combined Soft-Hard Layer Produced by Ligand Cross-Linking.

Project description:Although perovskite nanocrystals have attracted considerable interests as emerging semiconductors in optoelectronic devices, design and fabrication of a deformable structure with high stability and flexibility while meeting the charge transport requirements remain a huge challenge. Herein, a combined soft-hard strategy is demonstrated to fabricate intrinsically flexible all-inorganic perovskite layers for photodetection via ligand cross-linking. Perfluorodecyltrichlorosilane (FDTS) is employed as the capping ligand and passivating agent bound to the CsPbBr3 surface via Pb-F and Br-F interactions. The SiCl head groups of FDTS are hydrolyzed to produce SiOH groups which subsequently condense to form the SiOSi network. The CsPbBr3 @FDTS nanocrystals (NCs) are monodispersed cubes with an average particle size of 13.03 nm and exhibit excellent optical stability. Furthermore, the residual hydroxyl groups on the surface of the CsPbBr3 @FDTS render the NCs tightly packed and cross-linked to each other to form a dense and elastic CsPbBr3 @FDTS film with soft and hard components. The photodetector based on the flexible CsPbBr3 @FDTS film exhibits outstanding mechanical flexibility and robust stability after 5000 bending cycles.

| S-EPMC10401168 | biostudies-literature

Soft Nanomembrane Sensors and Flexible Hybrid Bioelectronics for Wireless Quantification of Blepharospasm.

Project description:Blepharospasm (BL) is characterized by involuntary closures of the eyelids due to spasms of the orbicularis oculi muscle. The gold standard for clinical evaluation of BL involves visual inspection for manual rating scales. This approach is highly subjective and error prone. Unfortunately, there are currently no simple quantitative systems for accurate and objective diagnostics of BL. Here, we introduce a soft, flexible hybrid bioelectronic system that offers highly conformal, gentle lamination on the skin, while enabling wireless, quantitative detection of electrophysiological signals. Computational and experimental studies of soft materials and flexible mechanics provide a set of key fundamental design factors for a low-profile bioelectronic system. The nanomembrane soft electrodes, mounted around the eyes, are capable of accurately measuring clinical symptoms, including the frequency of blinking, the duration of eye closures during spasms, as well as combinations of blinking and spasms. The use of a deep-learning, convolutional neural network, with the bioelectronics offers objective, real-time classification of key pathological features in BL. The wearable bioelectronics outperform the conventional manual clinical rating, as shown by a pilot study with 13 patients. In vivo demonstration of the bioelectronics with these patients indicates the device as an easy-to-use solution for objective quantification of BL.

| S-EPMC7604814 | biostudies-literature

Intra-Operative Bioprinting of Hard, Soft, and Hard/Soft Composite Tissues for Craniomaxillofacial Reconstruction.

Project description:Reconstruction of complex craniomaxillofacial (CMF) defects is challenging due to the highly organized layering of multiple tissue types. Such compartmentalization necessitates the precise and effective use of cells and other biologics to recapitulate the native tissue anatomy. In this study, intra-operative bioprinting (IOB) of different CMF tissues, including bone, skin, and composite (hard/soft) tissues, is demonstrated directly on rats in a surgical setting. A novel extrudable osteogenic hard tissue ink is introduced, which induced substantial bone regeneration, with ≈80% bone coverage area of calvarial defects in 6 weeks. Using droplet-based bioprinting, the soft tissue ink accelerated the reconstruction of full-thickness skin defects and facilitated up to 60% wound closure in 6 days. Most importantly, the use of a hybrid IOB approach is unveiled to reconstitute hard/soft composite tissues in a stratified arrangement with controlled spatial bioink deposition conforming the shape of a new composite defect model, which resulted in ≈80% skin wound closure in 10 days and 50% bone coverage area at Week 6. The presented approach will be absolutely unique in the clinical realm of CMF defects and will have a significant impact on translating bioprinting technologies into the clinic in the future.

| S-EPMC8376234 | biostudies-literature

Flexible all-polymer waveguide for low threshold amplified spontaneous emission.

Project description:The fabrication of all polymer optical waveguides, based on a highly fluorescent conjugated polymer (CP) poly(9,9-dioctylfluorene-alt-benzothiadiazole) (F8BT) and a mechanically flexible and biodegradable polymer, cellulose acetate (CA), is reported. The replication by hot embossing of patterned surfaces in CA substrates, onto which high quality F8BT films can be easily processed by spin coating, is exploited to produce an entirely plastic device that exhibits low optical loss and low threshold for amplified spontaneous emission (ASE). As a result, highly transparent and flexible waveguides are obtained, with excellent optical properties that remain unaltered after bending, allowing them to be adapted in various flexible photonic devices.

| S-EPMC5043348 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data