Efficient and stable noble-metal-free catalyst for acidic water oxidation.

ABSTRACT: Developing non-noble catalysts with superior activity and durability for oxygen evolution reaction (OER) in acidic media is paramount for hydrogen production from water. Still, challenges remain due to the inadequate activity and stability of the OER catalyst. Here, we report a cost-effective and stable manganese oxybromide (Mn_7.5O₁₀Br₃) catalyst exhibiting an excellent OER activity in acidic electrolytes, with an overpotential of as low as 295 ± 5 mV at a current density of 10 mA cm^-2. Mn_7.5O₁₀Br₃ maintains good stability under operating conditions for at least 500 h. In situ Raman spectroscopy, X ray absorption near edge spectroscopy, and density functional theory calculations confirm that a self-oxidized surfac

SUBMITTER: Pan S 

PROVIDER: S-EPMC9050677 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature