Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material co-doping strategy.

ABSTRACT: High-capacity Ni-rich layered oxides are promising cathode materials for secondary lithium-based battery systems. However, their structural instability detrimentally affects the battery performance during cell cycling. Here, we report an Al/Zr co-doped single-crystalline LiNi_0.88Co_0.09Mn_0.03O₂ (SNCM) cathode material to circumvent the instability issue. We found that soluble Al ions are adequately incorporated in the SNCM lattice while the less soluble Zr ions are prone to aggregate in the outer SNCM surface layer. The synergistic effect of Al/Zr co-doping in SNCM lattice improve the Li-ion mobility, relief the internal strain, and suppress the Li/Ni cation mixing upon cycling at high cut-off voltage. These features improve the cathode rate capab

SUBMITTER: Ou X 

PROVIDER: S-EPMC9050889 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature