Synthesis, crystal structures and, magnetic and photoluminescence properties of lanthanide-based metal-organic frameworks constructed with 2,5-dihydroxybenzene-1,4-dicarboxylic acid.

ABSTRACT: Four new lanthanide(iii) coordination polymers (1-4) have been synthesized by using 2,5-dihydroxybenzene-1,4-dicarboxylate (Dhbdc, C₈H₆O₆ ^2-) as a ligand and characterized by elemental analysis, infrared spectroscopy, TGA-DSC (Thermogravimetric Analysis-Differential Scanning Calorimetry) and single crystal X-ray diffraction studies. The isolated complexes include; [Ce(Dhbdc)(H₂O)₃Cl] _n (1) and [Ln(Dhbdc)_1.5(H₂O)₂] _n ·3n(C₂H₆O)·nH₂O [Ln = Eu (2), Gd (3) and Tb (4)]. The structural analysis reveals that compound 1 is a two-dimensional polymer in which the cerium atoms are coordinated by six oxygen and two bridgin

SUBMITTER: Hussain S 

PROVIDER: S-EPMC9051047 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature