In situ production of a two-dimensional molybdenum disulfide/graphene hybrid nanosheet anode for lithium-ion batteries.

ABSTRACT: A solvent-free, low-cost, high-yield and scalable single-step ball milling process is developed to construct 2D MoS₂/graphene hybrid electrodes for lithium-ion batteries. Electron microscopy investigation reveals that the obtained hybrid electrodes consist of numerous nanosheets of MoS₂ and graphene which are randomly distributed. The MoS₂/graphene hybrid anodes exhibit excellent cycling stability with high reversible capacities (442 mA h g^-1 for MoS₂/graphene (40 h); 553 mA h g^-1 for MoS₂/graphene (20 h); 342 mA h g^-1 for MoS₂/graphene (10 h)) at a high current rate of 250 mA g^-1 after 100 cycles, whereas the pristine MoS₂ electrode shows huge capacity fading with a retention of 37 mA h g^-1 at 250 mA g^-1 current after 100 cycles. The incorporation of graphene into MoS₂ has an extraordinary effect on its electrochemical performance. This work emphasises the importance of the construction of the 2D MoS₂/graphene hybrid structure to prevent capacity fading issues with the MoS₂ anode in lithium-ion batteries.

SUBMITTER: Mateti S 

PROVIDER: S-EPMC9051260 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature