Application of temperature-controlled chiral hybrid structures constructed from copper(ii)-monosubstituted Keggin polyoxoanions and copper(ii)-organoamine complexes in enantioselective sensing of tartaric acid.
Ontology highlight
ABSTRACT: Temperature usually occupies a crucial position in the construction of chiral compounds. By controlling the temperature of the reaction system, chiral and non-chiral compounds can be designed and synthesized. Given the above, three new chiral and non-chiral compounds based on copper(ii) monosubstituted polyoxoanions and Cu(en) complexes (en = ethylenediamine), d/l-[Cu(H2O)(en)2]2{[Cu(H2O)2(en)][SiCuW11O39]}·5H2O (1, d-1 and l-1) and [Cu(H2O)(en)2]{[Cu(en)2]2[SiCuW11O39]}·2.5H2O (2), were successfully synthesized under hydrothermal conditions. The main synthesis conditions of compound 1 (d-1 and l-1) and compound 2 are the same,
SUBMITTER: Yang MX
PROVIDER: S-EPMC9051601 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
ACCESS DATA
