Molecularly engineered electroplex emission for an efficient near-infrared light-emitting electrochemical cell (NIR-LEC).

ABSTRACT: Electroplex emission is rarely seen in ruthenium polypyridyl complexes, and there have been no reports from light-emitting electrochemical cells (LECs) to date. Here, for the first time, near-infrared (NIR) emission via the electroplex mechanism in a LEC based on a new blend of ruthenium polypyridyl complexes is described. The key factor in the design of the new complexes is the 0.4 V decrease in the oxidation half-potential of Ru(ii)/Ru(iii) in [Ru(DPCO)(bpy)₂]ClO₄ (DPCO = diphenylcarbazone, bpy = 2,2 bipyridine), which is about one-third of the value for benchmark [Ru(bpy)₃](ClO₄)₂, as well as the long lifetime of excited states of 350-450 ns. The LEC based on the new blend with a narrow band gap (≈1.0 eV) of a Ru(DPCO) comple

SUBMITTER: Shahroosvand H 

PROVIDER: S-EPMC9051648 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature