Poly(ethylene glycol)-poly(propylene glycol)-poly(ethylene glycol) and polyvinylidene fluoride blend doped with oxydianiline-based thiourea derivatives as a novel and modest gel electrolyte system for dye-sensitized solar cell applications.

ABSTRACT: Unique symmetrical thiourea derivatives with an oxydianiline core were synthesized using cost-effective and simple methods. A new gel electrolyte system was prepared using these thiourea additives along with a highly conductive PEG-PPG-PEG block copolymer, PVDF, and an iodide/triiodide redox couple. The PEG units present in the electrolyte are well-known for their intense segmental motion of ions, which can degrade the recombination rate and favour the charge transfer. The thiourea additives interacted well with the redox couple to limit iodine sublimation and their adsorption induced a negative potential shift for TiO₂. The highest efficiency attained by utilizing such gel polymer electrolytes was 5.75%, especially with 1,1'-(oxybis(4,1-phenylene))bis(3-(6-methylpyridin-2-yl) t

SUBMITTER: Karthika P 

PROVIDER: S-EPMC9052015 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature