Catalyzed M-C coupling reactions in the synthesis of σ-(pyridylethynyl)dicarbonylcyclopentadienyliron complexes.

ABSTRACT: The reactions between terminal ethynylpyridines, (trimethylsilyl)ethynylpyridines and cyclopentadienyliron dicarbonyl iodide were studied under Pd/Cu-catalyzed conditions to develop a synthetic approach to the σ-alkynyl iron complexes Cp(CO)₂Fe-C[triple bond, length as m-dash]C-R (R = ortho-, meta-, para-pyridyl). Depending on the catalyst and reagents used, the yields of the desired σ-pyridylethynyl complexes varied from 40 to 95%. In some cases the reactions with ortho-ethynylpyridine gave as byproduct the unexpected binuclear FePd μ-pyridylvinylidene complex [Cp(CO)Fe{μ₂-η¹(C_α):η¹(C_α)-κ¹(N)-C_α[double bond, length as m-dash]C_β(H)(o-C₅H₄

SUBMITTER: Verpekin VV 

PROVIDER: S-EPMC9053414 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature