Transformation of ZIF-8 nanoparticles into 3D nitrogen-doped hierarchically porous carbon for Li-S batteries.

ABSTRACT: Li-S batteries have been attracting increasing interest owing to their remarkable advantages of low cost, high theoretical capacity and high theoretical energy density. Nevertheless, the severe "shuttle effects" of lithium polysulfides have markedly limited the performance of the cells and further hindered their commercial applications. Herein, a novel scheme combining a transformation strategy with ammonia treatment was developed to fabricate ZIF-8-derived nitrogen-doped hierarchically porous carbon (NHPC/NH₃). When NHPC/NH₃ was used as a host of sulfur, the obtained S@NHPC/NH₃ cathode for Li-S cells presented an initial specific capacity of 1654 mA h g^-1 and an outstanding cycling stability with only 0.27% attenuation per cycle from the 30th cy

SUBMITTER: Cao G 

PROVIDER: S-EPMC9053475 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature