From cyclic amines and acetonitrile to amidine zinc(ii) complexes.

ABSTRACT: A seemingly simple combination of [Zn(quin)₂(H₂O)] (quin^- = quinaldinate) and a selected secondary cyclic amine, piperidine (pipe), pyrrolidine (pyro) or morpholine (morph), afforded in acetonitrile a number of products: anionic homoleptic quinaldinate, neutral heteroleptic quinaldinate/amine and quinaldinate/amidine complexes. The piperidine and pyrrolidine systems underwent reaction with acetonitrile to give amidines. The in situ formed piperidinoacetamidine (pipeam) or pyrrolidinoacetamidine (pyroam) coordinated to zinc(ii). Reactions with piperidine led to trans-[Zn(quin)₂(pipe)₂]·2CH₃CN (1), [Zn(quin)₂(pipe)]·cis-[Zn(quin)₂(pipe)₂] (2), pipeH[Zn(quin)₃]·CH

SUBMITTER: Podjed N 

PROVIDER: S-EPMC9053709 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature