Enhanced methane gas storage in the form of hydrates: role of the confined water molecules in silica powders.

ABSTRACT: Methane hydrates are promising materials for storage and transportation of natural gas; however, the slow kinetics and inefficient water to hydrate conversions impede its broad scale utilisation. The purpose of the present study is to demonstrate rapid (2-3 h) and efficient methane hydrate conversions by utilising the water molecules confined in the intra- and inter-granular space of silica powders. All the experiments were conducted with amorphous silica (10 g) powders of 2-30 μm; 10-20 nm grain size, to mimic the hydrate formations in fine sand and clay dominated environments under moderate methane pressure (7-8 MPa). Encasing of methane molecules in hydrate cages was confirmed by Raman spectroscopic (ex situ) and thermodynamic phase boundary measurements. The present studies reve

SUBMITTER: Prasad PSR 

PROVIDER: S-EPMC9053743 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature