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Compatibilization of porphyrins for use as high permittivity fillers in low voltage actuating silicone dielectric elastomers.


ABSTRACT: Polysiloxanes represent, because of their unusual properties, a material with great potential for use in dielectric elastomers (DEs), a promising class of electroactive polymers. Currently, their application as actuators is limited by the need for high driving voltages, as a result of the low relative permittivity possessed by polysiloxanes (∼2-3). Reducing these voltages can be achieved to some degree by using high permittivity additives to improve the permittivity of the polysiloxane. However, modifying such additives so that they are compatible with, and can be dispersed within, polysiloxane elastomers remains challenging. For reliable actuation, full miscibility is key. In this work the porphyrin 5,10,15,20-(tetra-3-methoxyphenyl)porphyrin (TPMP) was investigated as a high permittivity

SUBMITTER: Gale CB 

PROVIDER: S-EPMC9053863 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature