Pseudo-superparamagnetic behaviour of barium hexaferrite particles.

ABSTRACT: The effect of hexadecyltrimethylammonium bromide (CTAB) addition on the crystal structure, morphology, and magnetic properties of co-precipitated hexagonal barium ferrite was investigated. For a fixed amount of surfactant, different Fe³⁺ concentrations and Fe³⁺/Ba²⁺ ratios were used to optimize the formation of single-phase barium ferrite particles. The results indicated that the obtained ferrite particles exhibited coercivity changes similar to those of superparamagnetic particles with larger than theoretically calculated particle sizes. This results from the softening of the material due to the size reduction of the grains and incorporation of excess barium, localized on the surface of the particles. Therefore, lowering the energy barrier required to reve

SUBMITTER: Dudziak S 

PROVIDER: S-EPMC9053871 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature