Synthesis and characterization of TiO₂/Mg(OH)₂ composites for catalytic degradation of CWA surrogates.

ABSTRACT: Surface catalyzed reactions can be a convenient way to deactivate toxic chemical warfare agents (CWAs) and remove them from the contaminated environment. In this study, pure titanium oxide, magnesium hydroxide, and their composites TiO₂/Mg(OH₂) were prepared by thermal decomposition and precipitation of the titanium peroxo-complex and/or magnesium nitrate in an aqueous solution. The as-prepared composites were examined by XRD, XPS, HRTEM, and nitrogen physisorption. Their decontamination ability was tested on CWA surrogates and determined by high-performance liquid chromatography (HPLC) and gas chromatography coupled with mass spectrometry (GC-MS). Dimethyl methyl phosphonate (DMMP) was used as a G simulant for the nerve agents sarin (GB) and soman (GD) while 2-chloro

SUBMITTER: Stastny M 

PROVIDER: S-EPMC9054062 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature